Bis(μ-hydroxido-κ2 O:O)bis[bis(5-carboxypyridine-2-carboxylato-κ2 N,O 2)iron(III)] dihydrate
نویسنده
چکیده
The complete binuclear complex in [Fe2(C7H4NO4)4(OH)2]·2H2O, is generated by the application twofold symmetry. The Fe(III) atom is coordinated by the O atoms of two bridging hydroxyl groups and by two N and two O atoms from two pyridine-2,5-di-carboxyl-ato ligands, forming a distorted octa-hedral geometry. The Fe⋯Fe separation within the dinuclear complex is 3.0657 (4) Å. In the crystal, O-H⋯O and C-H⋯O hydrogen-bonding inter-actions connect the mol-ecules into a three-dimensional supra-molecular network.
منابع مشابه
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